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481.
2000年受La Nina结束后冷水事件的影响,北半球大气环充的要主特征表现为:500hPa东亚中纬度呈经,纬向环流交替分布,西太平洋副热带高压偏弱,偏北,偏东,热带对流活动冬季偏强,夏季偏弱,赤道辐合带偏弱,在上述大气环流的影响下,台风偏少,夏季主要多雨带位于黄河与长江之间,黄河以北地区干旱严重。 相似文献
482.
Groundwater of the coastal plain of the Rio de La Plata, Argentina,contains up to 17 g L-1 SO4 and 37 gL-1 TDS. Some of this SO4 is from paleo-seawater intrusion; however, SO4 : Cl ratios can be>2 : 1, and most of the SO4 must, therefore, have another source. Three possible sources were investigated: gypsum, organic matter,and iron sulphides.
Dissolved SO4 showed δ34S valuesfrom -7 to 0‰, typical values for S from iron sulphides or organicmatter, but distinct from that of seawater (+22‰).
To test whetherthe SO4 was derived from oxidation of reduced S, four 4-mcores were taken from marine sediments of the coastal plain. Two were takenfrom
higher, drier areas where the highest dissolved SO4values were encountered, and two were taken from lower, wetter areas thathad much lower SO4 concentrations. Pore waterSO4, Cl and alkalinity were determined; solids were analyzedfor SO4, sulphide-S and organic-S.
Sulphide-S was the dominant form of reduced S, averaging about0.5% S in the lower interval (2.5–4 m) of the cores. Sulphidewas
absent in the upper 2.5 m in both topographically higher and lowerareas. Sulphate was present in the entire unit in the higher,
drier areas,but almost absent in lower areas. Organic-S was insignificant.
Our model for the origin of dissolved SO4 is: fine-grainedpyrite was oxidized during hotter or drier periods. Some resulting dissolvedSO4 was precipitated as gypsum. Iron from the pyriteprecipitated as FeOOH. Lower, wetter areas formed over time where recharginggroundwater
dissolved most of the gypsum. In higher areas with low hydraulicgradients and high net evapotranspiration, SO4 remained asgypsum and in the dissolved phase.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
483.
Approaches to equilibrium in the distribution of trace elements among the principal minerals in a high-grade metamorphic terrane 总被引:2,自引:0,他引:2
X-ray fluorescence, instrumental neutron activation, and particle-induced X-ray emission methods were used to determine the distribution of numerous trace elements among garnet (Grt), Ca-pyroxene (Cpx), hornblende (Hbl), biotite (Bt), plagioclase (Pl) and K-feldspar (Kf) in a high-grade metamorphic terrane within the Grenville Province of the Canadian Shield. Results are presented as distribution formulae, e.g. Sr: Kf 1.1 Pl 16 Hbl 2.2 Cpx 1.0 Bt 1.2 Grt Sc: Hbl 1.1 Cpx 1.0 Grt 7.8 Bt 22 Pl 2.6 Kf V: Hbl 1.15 Bt 2.07 Cpx 6.0 Grt (1.4% CaO)>1 (Pl, Kf) Zn: Bt 1.6 Hbl 1.62 Cpx 2.9 Grt 10 Pl Ga: Bt 1.2 Hbl 1.2 Pl 2.5 Cpx 1.3 Grt where numbers are distribution ratios, e.g. ppm Sr in Hbl/ppm Sr in Cpx=2.2. Examples of inter-element similarities and differences are (a) both Rb and Cs are concentrated in biotite relative to K-feldspar, but for Rb the ratio is 2.3 and for Cs it is 16, (b) the distribution formulae for seven lanthanides are similar except for the position of garnet, e.g. Ce: Hbl 2.7 Cpx 2.8 Pl 1.1 Bt 11 Kf 16 Grt Yb: Grt 2.8 Hbl 2.7 Cpx 9 Pl 1.0 Bt 7 Kf and (c) all of Sr, eight lanthanides, Zr, V and Cr are concentrated in hornblende relative to Ca-pyroxene by a factor that lies in the narrow range of 2.2–3.1. There is a larger variation (departure from the mean) in some distribution ratios than in others. Thus the mean ratios (Hbl/Cpx) for each of six elements and in parentheses the percentage relative standard deviation are Zn 1.62 (8.6), V 2.38 (12), Cr 2.42 (18), Sr 2.7 (28), Ba 2.9 (36) and Ni 1.66 (38). We suggest that variation of this kind is the result of differences from place to place in the magnitude of deformation and recrystallization (which facilitated the rearrangement of atoms), combined with rates of lattice and crystal-boundary diffusion that are unique for the various elements, thus permitting some trace elements to approach equilibrium more closely than others. 相似文献
484.
在经济高速发展的今天,必须注意保护和改善我们赖以生存的地球环境:既要尽量减少污染,又需加强对已有污染物的处理。能源(煤、石油、天然气)的利用是工业革命的强大推动力,但也是污染地球环境的主要来源。因此,我们必须提高能源的利用效率,减少其中污染物的含量,从而减少能源的利用对环境的污染,同时加强治理能源工业和利用所产生的污染物,例如石油残渣。在石油和液化煤的提炼过程,所利用的主要是催化的氢化和氢气裂解反应。工业上最常用的催化剂是以γAl2O3为载体,Co或Ni为促进剂的Mo或W的硫化物。但是,由于北… 相似文献
485.
青海拉脊山东段水系沉积物地球化学测量,发现金源、喇嘛庙、七里寺峡Au、As、Ag、Bi、Sb、Hg等元素的水系沉积物组合异常.Au、Ag、As相对高浓度带发育形态、分布范围、异常浓集中心吻合,与区内已知尼旦沟金矿床地球化学异常特征可以类比,发现有金、铜矿体和金矿化,显示铜金成矿的有望远景地段. 相似文献
486.
Diatom and chrysophyte assemblages from a sediment core from Whitepine Lake were examined to infer changes in lakewater pH, nickel and aluminum concentrations since pre-industrial times, and to help determine the cause of the virtual extirpation of the lake trout population from the lake during the 1960s and 1970s. Our study indicates that acidification started in the 1920s, and that the maximum inferred pH decline (from 6.2 to 5.8) occurred between 1960 and 1970, coincident with the peak in metal mining and smelting activity in the Sudbury basin. Lakewater [Al] and [Ni], as inferred from our diatom transfer functions, increased. It appears that in addition to the pH decline, elevated [Al] may have played an important role in the decline of lake trout from Whitepine Lake in the 1960s and 1970s. Diatom-inferred lakewater pH and [Ni] have recovered slightly in the recent sediments, which coincides with reductions in emissions that have occurred since the mid-1970s. 相似文献
487.
本文研究了Fe(Ⅲ),Co(Ⅱ),Ni(Ⅱ.),Cu(Ⅱ)在5-Br-PADAP-TritonX-100体系中的析相显色反应。利用该体系具有一定选择性和富集、分离的特点,采用多波长K系数法,根据公式ΔA=A-sum from i=1 to n K_iA_i=KC,在一个测定波长和与干扰组分个数相等的参比波长下,测定混合多组分体系的吸光度。求得相应K值后,再计算各待测组分含量。本法用于测定人发中微量铁、钴、镍、铜取得了满意结果。 相似文献
488.
The contents of Ni and Cr in sewage sludge with high and low amounts of heavy metals were investigated by polarography. The DIN-digestion (aqua regia) was used, and the resulting solution was treated with H2O2/UV (90 °C, 60 min) for further destroying of the organic material. Besides, the solution of the DIN-digestion was examined with AAS (flame) and ICP-OES. With the determination of Ni it was shown that after digestion with aqua regia no further treatment with H2O2/UV is necessary. Contrariwise it was found that for the determination of Cr a H2O2/UV photolysis is necessary followed by further steps to get good agreement with AAS and ICP results as well as with the certified values of a sludge of the Community Bureau of Standards. 相似文献
489.
金川硫化铜镍矿床成矿岩浆性质和源区特征讨论 总被引:12,自引:0,他引:12
通过对造岩矿物、岩石化学和铂族元素等信息的综合分析,认为金川岩体的母岩浆属拉斑玄武质苦橄岩浆,是地幔橄榄岩经33%部分熔融的产物;硫、钕、锶、氧等同位素资料说明岩浆源区可能在上地幔低速层底部,属富集型地幔 相似文献
490.